1. Synonyms
Acetate de methyle;methyle(acetatede);methyle(acetatede)(french);Methylester kiseliny octove;methylesterkiselinyoctove;methylesterkiselinyoctove(czech);methylethanoate;Metile
2. Usage
1-Butanol, also known as n-butanol or butyl alcohol, is a four-carbon alcohol with the chemical formula C4H9OH. It is a colorless liquid with a slightly sweet odor.
1-Butanol has various uses in different industries. Some of the common applications of 1-Butanol are:
- Solvent: It is widely used as a solvent in many industries, including paint, coatings, and inks. 1-Butanol is an effective solvent for resins, dyes, oils, and other organic compounds. It helps in dissolving and dispersing solid components, enhancing the flow and application of various products.
- Chemical Manufacturing: 1-Butanol is a vital starting material for the production of other chemicals. It is used in the manufacturing of esters, plasticizers, butyl acrylate, butyl acetate, butyl glycol ethers, and other chemicals.
- Extractant: It is used as an extractant in various extraction processes. 1-Butanol is commonly employed in the extraction of natural products, such as flavors, fragrances, and pharmaceuticals, from plant materials.
- Biofuel: 1-Butanol has gained attention as a potential biofuel and is considered an alternative to gasoline. It can be produced from biomass through various fermentation processes, making it a renewable and eco-friendly fuel option.
- Intermediate: 1-Butanol is used as an intermediate compound in the synthesis of pharmaceuticals, perfumes, and other specialty chemicals.
- Cleaning Agent: It is used in the manufacturing of cleaning agents, detergents, and degreasers due to its solvent properties.
It is important to note that the usage of 1-Butanol should be in accordance with safety guidelines and regulations to ensure proper handling and minimize any potential risks.
3. COA
SHANDONG FENGCANG CHEMICAL CO., LTD. HUANTAI,ZIBO,SHANDONG |
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Certificate of Analysis | |||
Commodity | Butyl alcohol | Test Standard | GB/T6027-1998 |
Quantity | 23.80(MT) | Inspection date | 20201010 |
Production batch number | 3703W7119013 | Expiry date | 20211009 |
Items | Index | Test Result | Test method |
Superior Grade Products | |||
Appearance | Transparent liquid,no visible impurities | Pass | GB/T6027-1998 |
Chromaticity/Hazen,(Pt-Co) ≤ | 10 | 5 | GB/T 3143-82 |
Acidity(as acetic acid),% ≤ | 0.003 | 0.002 | GB 6324.2-86 |
Evaporation residue , % ≤ | 0.003 | 0.002 | GB/T 6324.2-1986 |
Chromogenic sulfate experiment, (Pt-Co) ≤ |
20 | 10 | GB/T 6027-1998 |
Moisture,% ≤ | 0.1 | 0.04 | GB/T 6283-86 |
Density,g/cm3 | 0.809-0.811 | 0.81 | GB/T 4472 2.3 3-84 |
Purity, % ≥ | 99.5 | 99.9 | GB/T 6027-1998 |
Note | Superior Grade Products |
4. MSDS
Chemical Safety Data Sheet Section 1 IDENTIFICATION |
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GHS Product identifier: 1-Butanol. Other means of identification: / Recommended use of the chemical and restrictions on use: This material can be used as chromatographic analysis reagent and food perfume. It can also be used in organic synthesis. Supplier’s details: / Emergency phone number: / |
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Section 2 HAZARDS IDENTIFICATION | ||||||||||||||||||||
Flammable liquids Category 3 Acute toxicity, oral Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Specific target organ toxicity, single exposure; Respiratory tract irritation Category 3 Specific target organ toxicity, single exposure; Narcotic effects Category 3 GHS Label elements, including precautionary statements: Signal word: Danger Hazard statement(s): Flammable liquid and vapor. Harmful if swallowed. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation. May cause drowsiness or dizziness. Precautionary statement(s): Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed. Ground/Bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Response: In case of fire: Use water spray, foam or chemical powder to extinguish. If swallowed: Call a poison center/doctor if you feel unwell. Rinse mouth. If on skin (or hair): Rinse skin with water/shower. Specific treatment (see under for further information). If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. |
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Storage: Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with local/regional/national/international regulations. Other hazards which do not result in classification: / |
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Section 3 COMPOSITION/INFORMATION ON INGREDIENTS | ||||||||||||||||||||
Chemical Name | CAS No. | Concentration% | ||||||||||||||||||
1-Butanol | 71-36-3 | 99.86% | ||||||||||||||||||
Section 4 FIRST AID MEASURES | ||||||||||||||||||||
Description of necessary first aid measures If inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact: Wash off with soap and plenty of water. Consult a physician. In case of eye contact: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If Ingestion: Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms/effects, acute and delayed: / Indication of immediate medical attention and special treatment needed, if necessary: / |
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Section 5 FIREFIGHTING MEASURES | ||||||||||||||||||||
Suitable extinguishing media: Use alcohol-resistant foam, chemical powder or water spray. Special hazards arising from the chemical: Liquid and vapour are flammable. May explode and burn in high temperature and fire and release toxic fumes. Special protective actions for fire-fighters: Wear self-contained breathing apparatus for firefighting if necessary. Use water spray to cool unopened containers. |
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Section 6 ACCIDENTAL RELEASE MEASURES | ||||||||||||||||||||
Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and materials for containment and cleaning up: Contain spillage and then collect with pump and place in a clean container for disposal according to local regulations. |
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Precautions for safe handling: Wear protective gloves/eye protection/face protection/protective clothing. Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking. Conditions for safe storage, including any incompatibilities: Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Keep away from flammable materials and oxidizers. |
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Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | ||||||||||||||||||||
Control parameters: Source Material name TWA China Occupational Exposure Limits for Hazardous Agents 1-Butanol 100 (mg/m3) in the Workplace Appropriate engineering controls: Local exhaust ventilation or a process enclosure ventilation system may be required. Individual protection measures Eye/face protection: Safety glasses with side shields. Chemical goggles. Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. Skin protection: Wear chemical protective gloves, e.g. PVC. Wear safety footwear or safety gumboots, e.g. Rubber. Impervious clothing, Respiratory protection: Selection of the Class and Type of respirator will depend upon the level of breathing zone contaminant and the chemical nature of the contaminant. Thermal hazards: / |
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Section 9 PHYSICAL AND CHEMICAL PROPERTIES | ||||||||||||||||||||
Appearance (physical state, colour etc) | Colorless transparent liquid. | |||||||||||||||||||
Odour | / | |||||||||||||||||||
Odour Threshold | / | |||||||||||||||||||
pH | / | |||||||||||||||||||
Melting point/freezing point | -90℃. | |||||||||||||||||||
Initial boiling point and boiling range | 117℃. | |||||||||||||||||||
Flash point | 38.0℃. | |||||||||||||||||||
Evaporation rate | / | |||||||||||||||||||
Flammability (solid, gas) | / | |||||||||||||||||||
Upper/lower flammability or explosive limits | 1.4%~11.3%. | |||||||||||||||||||
Vapour pressure | 0.58kPa (20℃). | |||||||||||||||||||
Vapour density | 2.6. | |||||||||||||||||||
Relative density | 0.81. | |||||||||||||||||||
Solubility(ies) | 7.7g/100ml (20℃). | |||||||||||||||||||
Partition coefficient: n-octanol/water | 0.9. | |||||||||||||||||||
Auto-ignition temperature | 345℃. | |||||||||||||||||||
Decomposition temperature | / | |||||||||||||||||||
Viscosity | / | |||||||||||||||||||
Section 10 STABILITY AND REACTIVITY | ||||||||||||||||||||
Reactivity: / Chemical stability: This material is stable in normal temperature. Possibility of hazardous reactions: Reacts with aluminum when heated to 100 ℃ and strong oxidants such as chromium trioxide. This produces flammable/explosive gas hydrogen. Attacks some forms of plastic, rubber and coatings. Conditions to avoid: Spark, high temperature and static electricity. Incompatible materials: Flammable materials, aluminum and oxidizers. Hazardous decomposition products: Oxycarbides. |
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Section 11 TOXICOLOGICAL INFORMATION | ||||||||||||||||||||
Information on the likely routes of exposure: Inhaled, swallowed, skin, eyes. Symptoms related to the physical, chemical and toxicological characteristics: / Acute health effects: Accidental ingestion of the material may be harmful and cause cough, throat pain, dizziness and drowsiness. Oral intake cause headache, giddiness, vomit and other symptoms. This material may produce skin and eyes irritation. Chronic health effects: The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form of dermatitis is often characterized by skin redness (erythema) and swelling the epidermis. Numerical measures of toxicity(such as acute toxicity estimates): TOXICITY IRRITATION Dermal (rabbit) LD50: 3400 mg/kg Eye (human): 50 ppm - irritant Inhalation (human) TCLo: 25 ppm Eye (rabbit): 1.6 mg-SEVERE Inhalation (human) TCLo: 86000 mg/m3 Eye (rabbit): 24 mg/24h-SEVERE Inhalation (rat) LC50: 8000 ppm/4h Skin (rabbit): 405 mg/24h-moderate Oral (rat) LD50: 790 mg/kg |
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Section 12 ECOLOGICAL INFORMATION | ||||||||||||||||||||
Toxicity: / Persistence and degradability: / Bioaccumulative potential: / Mobility in soil: / Other adverse effects: / |
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Section 13 DISPOSAL CONSIDERATIONS | ||||||||||||||||||||
Disposal methods: Burial in a land-fill specifically licensed to accept chemical. Reuse of broken container is forbidden. |
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UN number: 1120. UN proper shipping name: BUTANOLS. Transport hazard class(es) : 3. Packing group, if applicable: III. Environmental hazards: / Special precautions for user: / |
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Section 15 REGULATORY INFORMATION | ||||||||||||||||||||
Regulations: This safety data sheet is in compliance with the following national standards: GB 16483-2008, GB 13690-2009, GB/T 15098-2008, GB 18218-2009, GB 15258-2009, GB 6944-2012, GB 190-2009, GB 191-2009, GB 12268-2008, GA 57-1993, GBZ 2-2007 as well as the following national regulations: Dangerous Goods Transport Administrative Regulation [Published by the Ministry of Railways, 2008], Dangerous Chemicals Safety Administrative Regulation [Published by the State Council, 2011]. |
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Section 16 OTHER INFORMATION | ||||||||||||||||||||
References | UN Recommendations on the Transport of Dangerous Goods Model Regulations UN Globally Harmonized System of Classification and Labelling of Chemicals |
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Form Date | 08-06-2015 | |||||||||||||||||||
Note 1: When products contain two or more hazardous substances, Safety Data Sheets should be prepared based on the risk of the mixture. Note 2: Manufacturer / supplier should ensure the correctness of the information contained in the safety data sheets, and updated in a timely manner. Note 3: As a result of product features without the existence of certain information or no data available (such as boiling point does not exist for the solid) in the table with "/" logo. |
Q&A
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